|
|
UDP-glucose + p-coumaric_acid <=> UDP + 4''-O-beta-D-glucosyl-cis-p-coumarate + H+
|
2.4.1.209
cis-p-coumarate glucosyltransferase
|
–
|
|
|
BRENDA:
BR29475
KEGG:
R05324
MetaCyc:
2.4.1.209-RXN
|
|
|
|
UDP-glucose + p-coumaric_acid <=> 4-O-beta-D-glucosyl-4-hydroxycinnamate + UDP + H+
|
2.4.1.126
hydroxycinnamate 4-beta-glucosyltransferase
2.4.1.237
flavonol 7-O-beta-glucosyltransferase
2.4.1.35
phenol beta-glucosyltransferase
|
–
–
–
|
|
|
BRENDA:
BR47647
KEGG:
R02951
MetaCyc:
2.4.1.126-RXN
|
|
|
|
L-tyrosine <=> p-coumaric_acid + NH3
|
4.3.1.23
tyrosine ammonia-lyase
4.3.1.24
phenylalanine ammonia-lyase
4.3.1.25
phenylalanine/tyrosine ammonia-lyase
5.4.3.6
tyrosine 2,3-aminomutase
|
–
–
–
–
|
MK
|
|
BRENDA:
BR48920
KEGG:
R00737
MetaCyc:
RXN-9697
SABIO-RK:
1100
|
|
|
|
p-coumaric_acid + H+ <=> 4-vinylphenol + CO2
|
4.1.1.102
phenacrylate decarboxylase
|
–
|
K
|
|
BRENDA:
BR51532
KEGG:
R02952
MetaCyc:
RXN-802
SABIO-RK:
2808
|
|
|
|
4-coumaroyl-CoA + (R)-3-(4-hydroxyphenyl)lactate <=> p-coumaric_acid + (R)-3-(4-hydroxyphenyl)lactoyl-CoA
|
2.8.3.17
3-(aryl)acryloyl-CoA:(R)-3-(aryl)lactate CoA-transferase
|
–
|
BM
|
|
BRENDA:
BR52901
KEGG:
R12492
MetaCyc:
RXN-19897
|
|
|
|
p-coumaric_acid + CoA + ATP <=> 4-coumaroyl-CoA + AMP + diphosphate
|
6.2.1.12
4-coumarate---CoA ligase
6.2.1.2
medium-chain acyl-CoA ligase
6.2.1.30
phenylacetate---CoA ligase
|
–
–
–
|
BMK
|
|
BRENDA:
BR63
KEGG:
R01616
MetaCyc:
4-COUMARATE--COA-LIGASE-RXN
SABIO-RK:
1761
|
|
|
|
p-coumaric_acid + O2 + FADH2 <=> caffeic_acid + H2O + FAD + H+
|
1.14.14
1.14.14.9
4-hydroxyphenylacetate 3-monooxygenase
|
–
–
|
M
|
|
BRENDA:
BS428032
MetaCyc:
RXN-14988
|
|
|
|
trans-cinnamate + reduced_flavodoxin + O2 <=> p-coumaric_acid + flavin + H2O
|
1.14.14.91
trans-cinnamate 4-monooxygenase
|
–
|
BK
|
|
BRENDA:
BR33713
KEGG:
R02253
|
|
|
|
4-hydroxyphenylpropionic_acid + flavin <=> p-coumaric_acid + reduced_flavodoxin
|
1.3.8.15
3-(aryl)acrylate reductase
|
–
|
B
|
|
BRENDA:
BR52970
KEGG:
R12534
|
|
|
|
UDP-glucose + p-coumaric_acid <=> UDP + p-coumaroyl-beta-D-glucose
|
2.4.1.120
sinapate 1-glucosyltransferase
2.4.1.121
indole-3-acetate beta-glucosyltransferase
2.4.1.126
hydroxycinnamate 4-beta-glucosyltransferase
2.4.1.136
gallate 1-beta-glucosyltransferase
2.4.1.177
cinnamate beta-D-glucosyltransferase
|
–
–
–
–
–
|
|
|
BRENDA:
BS322020
KEGG:
R08534
SABIO-RK:
14462
|
|
|
|
methyl_p-coumarate + H2O <=> p-coumaric_acid + methanol
|
3.1.1.42
chlorogenate hydrolase
3.1.1.73
feruloyl esterase
|
–
–
|
|
|
BRENDA:
BS139680
SABIO-RK:
7120
|
|
|
|
4-hydroxybenzoate + acetate + NADH + H+ <=> p-coumaric_acid + 2 H2O + NAD+
|
not assigned
|
–
|
|
|
KEGG:
R01308
|
|
|
|
p-coumaric_acid + O2 + caffeic_acid <=> caffeic_acid + H2O + (2E)-3-(3,4-dioxocyclohexa-1,5-dien-1-yl)prop-2-enoic_acid
|
1.14.18.1
tyrosinase
|
–
|
|
|
KEGG:
R02950
|
|
|
|
p-coumaric_acid <=> caffeic_acid
|
1.14.13
|
–
|
K
|
|
KEGG:
R07826
|
|
|
|
p-coumaric_acid <=> Naringin_chalcone
|
not assigned
|
–
|
|
|
KEGG:
R08023
|
|
|
|
p-coumaric_acid <=> 3,4-Dihydroxybenzaldehyde
|
not assigned
|
–
|
K
|
|
KEGG:
R08435
|
|
|
|
(R)-3-(4-hydroxyphenyl)lactate <=> p-coumaric_acid + H2O
|
4.2.1
|
–
|
K
|
|
KEGG:
R08766
|
|
|
|
p-coumaric_acid + reduced_[NADPH-hemoprotein_reductase] + O2 <=> caffeic_acid + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14.96
5-O-(4-coumaroyl)-D-quinate 3'-monooxygenase
|
–
|
M
|
|
MetaCyc:
RXN-1103
|
|
|
|
p-coumaric_acid <=> 2,4-dihydroxycinnamic_acid
|
1
|
–
|
M
|
|
MetaCyc:
RXN-14167
|
|
|
|
p-coumaric_acid + NH3 <=> 3-amino-3-(4-hydroxyphenyl)propanoate
|
not assigned
|
–
|
|
|
MetaCyc:
RXN-18526
|
|
|
|
4-hydroxyphenylpropionic_acid + oxidized_electron_transfer_flavoprotein + H+ <=> p-coumaric_acid + reduced_flavodoxin
|
1.3.8.15
3-(aryl)acrylate reductase
|
–
|
M
|
|
MetaCyc:
RXN-19888
|
|
|
|
p-coumaric_acid + H2O <=> 4-hydroxybenzaldehyde + acetate
|
3.7.1
|
–
|
M
|
|
MetaCyc:
RXN-8871
|
|
|
|
Cinnamic_acid + O2 + reduced_[NADPH-hemoprotein_reductase] <=> p-coumaric_acid + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14.91
trans-cinnamate 4-monooxygenase
|
–
|
M
|
|
MetaCyc:
TRANS-CINNAMATE-4-MONOOXYGENASE-RXN
|
|
|
|
dimethylallyl_diphosphate + p-coumaric_acid <=> diphosphate + 3-dimethylallylcoumarate
|
2.5.1.111
4-hydroxyphenylpyruvate 3-dimethylallyltransferase
|
–
|
|
|
BRENDA:
BS423329
|
|
|
|
dimethylallyl_diphosphate + p-coumaric_acid <=> diphosphate + 4-O-dimethylallylcoumarate
|
2.5.1.111
4-hydroxyphenylpyruvate 3-dimethylallyltransferase
|
–
|
|
|
BRENDA:
BS423330
|
|
|
|
4-sulfocinnamic_acid + H2O <=> p-coumaric_acid + sulfate
|
3.1.6.1
arylsulfatase
|
–
|
|
|
BRENDA:
BS447961
|
|
|
|
4-hydroxycinnamonitrile + H2O <=> p-coumaric_acid + NH3
|
3.5.5.5
arylacetonitrilase
|
–
|
|
|
BRENDA:
BS397445
|
|
|
|
Cinnamic_acid + reduced_flavodoxin + O2 <=> p-coumaric_acid + flavin + H2O
|
1.14.14.92
benzoate 4-monooxygenase
|
–
|
|
|
BRENDA:
BS289256
|
|
|
|
p-coumaric_acid + O2 + reduced_acceptor <=> caffeic_acid + H2O + A
|
1.14.18.1
tyrosinase
1.14.99.15
4-methoxybenzoate monooxygenase (O-demethylating)
|
–
–
|
|
|
BRENDA:
BS353328
|
|
|
|
p-coumaric_acid + O2 <=> caffeic_acid + H2O
|
1.14.18.1
tyrosinase
|
–
|
|
|
BRENDA:
BS406274
|
|
|
|
4-coumaroyl-CoA + H2O <=> p-coumaric_acid + CoA
|
3.1.2.4
3-hydroxyisobutyryl-CoA hydrolase
|
–
|
|
|
BRENDA:
BS412641
|
|
|
|
xylan + H2O <=> ferulic_acid + p-coumaric_acid
|
3.1.1.73
feruloyl esterase
|
–
|
|
|
BRENDA:
BS139671
|
|
|
|
p-coumaric_acid + NAD+ <=> 4-hydroxyphenylpropionic_acid + NADH + H+
|
1.3.1.31
2-enoate reductase
|
–
|
|
|
BRENDA:
BS438836
|
|
|
|
p-Coumaroylcholine <=> p-coumaric_acid + choline
|
3.1.1.49
sinapine esterase
|
–
|
|
|
BRENDA:
BS64556
|
|
|
|
p-coumaric_acid + NADPH + ATP <=> 4-coumaraldehyde + NADP+ + AMP + H2O
|
1.2.1.30
carboxylate reductase (NADP+)
|
–
|
|
|
BRENDA:
BS189194
|
|
|
|
UDP-glucose + p-coumaric_acid <=> UDP + p-coumaroyl-beta-D-glucose + 4-O-glucosyl-p-coumaric_acid
|
2.4.1.126
hydroxycinnamate 4-beta-glucosyltransferase
|
–
|
|
|
BRENDA:
BS356094
|
|
|
|
UDP-glucose + p-coumaric_acid <=> UDP + 4-O-glucosylcoumaric_acid
|
2.4.1.104
o-dihydroxycoumarin 7-O-glucosyltransferase
|
–
|
|
|
BRENDA:
BS321958
|
|
|
|
UDP-glucose + p-coumaric_acid <=> UDP + p-coumaroyl_3-O-beta-D-glucoside
|
2.4.1.35
phenol beta-glucosyltransferase
|
–
|
|
|
BRENDA:
BS456915
|
|
|
|
5-O-p-coumaroylquinic_acid + H2O <=> p-coumaric_acid + quinate
|
3.1.1.73
feruloyl esterase
|
–
|
|
|
BRENDA:
BS391025
|
|
|
|
p-coumaric_acid + Br- + H+ + H2O2 <=> trans-1-Bromo-2-(4-hydroxyphenyl)ethylene + H2O
|
1.11.1.10
chloride peroxidase
|
–
|
|
|
BRENDA:
BS231275
|
|
|
|
N-p-Coumaroylglycine + H2O <=> p-coumaric_acid + glycine
|
3.5.1.71
N-feruloylglycine deacylase
|
–
|
|
|
BRENDA:
BS140656
|
|
|
|
ethyl_p-coumarate + H2O <=> p-coumaric_acid + ethanol
|
3.1.1.73
feruloyl esterase
|
–
|
|
|
BRENDA:
BS139660
|
|
|
|
p-coumaric_acid + Cl- + H+ + H2O2 <=> trans-1-chloro-2-(4-hydroxyphenyl)ethylene + H2O
|
1.11.1.10
chloride peroxidase
|
–
|
|
|
BRENDA:
BS231233
|
|
|
|
4-nitrophenyl_sulfate + p-coumaric_acid <=> 4-nitrophenol + 4-sulfocinnamic_acid
|
2.8.2.1
aryl sulfotransferase
|
–
|
|
|
BRENDA:
BS436919
|
|
|
|
p-coumaryl_beta-D-glucoside <=> p-coumaric_acid + beta-D-glucose
|
3.2.1.126
coniferin beta-glucosidase
|
–
|
|
|
BRENDA:
BS393063
|
|
|
|
O-5-O-(trans-p-coumaroyl)-alpha-L-arabinofuranosyl-(1-3)-O-beta-D-xylopyranosyl-(1-4)-D-xylopyranose + H2O <=> p-coumaric_acid + alpha-L-arabinofuranosyl-(1-3)-O-beta-D-xylopyranosyl-(1-4)-D-xylopyranose
|
3.1.1.73
feruloyl esterase
3.1.1.B10
|
–
–
|
|
|
BRENDA:
BS139684
|
|
|
|
beta-D-xylopyranosyl-(1->2)-5-O-[(2E)-3-(4-hydroxyphenyl)prop-2-enoyl]-alpha-L-arabinofuranosyl-(1->3)-beta-D-xylopyranosyl-(1->4)-D-xylopyranose + H2O <=> beta-D-xylopyranosyl-(1->2)-alpha-L-arabinofuranosyl-(1->3)-beta-D-xylopyranosyl-(1->4)-D-xylopyranose + p-coumaric_acid
|
3.1.1.B10
|
–
|
|
|
BRENDA:
BS435355
|
|
|
|
3,4-dihydroxyphenylpropanoyl-CoA + p-coumaric_acid <=> 3,4-Dihydroxyphenylpropionate + 4-coumaroyl-CoA
|
2.8.3.23
caffeate CoA-transferase
|
–
|
|
|
BRENDA:
BS431336
|
|
|
|
p-coumaroyl-beta-D-glucose + cyanidin_3-O-[[2-O-(2-O-sinapoyl)-beta-D-xylosyl]-6-O-(6-O-(4-coumaroyl)-beta-D-glucoside]_5-O-(6-O-malonyl)-beta-D-glucoside <=> p-coumaric_acid + cyanidin_3-O-[2-O-(2-O-(sinapoyl)-beta-D-xylosyl)-6-O-(6-(4-O-beta-D-glucosyl)-4-coumaroyl)-beta-D-glucoside]_5-O-[6-O-(malonyl)-beta-D-glucoside]
|
2.4.1.B70
|
–
|
|
|
BRENDA:
BR51671
|
|
|
|
p-coumaroyl-beta-D-glucose + cyanidin-3-O-rutinoside <=> p-coumaric_acid + cyanidin_3-O-rutinoside-7-O-beta-D-glucoside
|
2.4.1.300
cyanidin 3-O-glucoside 7-O-glucosyltransferase (acyl-glucose)
|
–
|
|
|
BRENDA:
BS435691
|
|
|
|
p-coumaric_acid + 2-phenylethyl_bromide <=> 2-phenylethyl_p-coumarate + Br-
|
3.1.1.42
chlorogenate hydrolase
|
–
|
|
|
BRENDA:
BS382452
|
|
|
|
p-coumaroyl-beta-D-glucose + cyanidin_3-O-beta-D-glucoside <=> p-coumaric_acid + cyanidin_3,5-di-O-beta-D-glucoside
|
2.4.1.299
cyanidin 3-O-glucoside 5-O-glucosyltransferase (acyl-glucose)
|
–
|
|
|
BRENDA:
BS422272
|
|
|
|
a_((E)-4-coumaroyl)-polysaccharide + H2O <=> p-coumaric_acid + a_polysaccharide
|
3.1.1.B10
|
–
|
|
|
BRENDA:
BR51688
|
|
|
|
cell_wall_((E)-4-coumaroyl)-polysaccharide + H2O <=> p-coumaric_acid + a_cell_wall_polysaccharide
|
3.1.1.B10
|
–
|
|
|
BRENDA:
BS435388
|
|
|
|
4-hydroxyphenylpropionic_acid + electron-transfer_flavoprotein_EtfA-EtfB <=> p-coumaric_acid + reduced_electron-transfer_flavoprotein_EtfA-EtfB
|
1.3.8.15
3-(aryl)acrylate reductase
|
–
|
|
|
BRENDA:
BS454460
|
|
|
|
p-coumaroyl-beta-D-glucose + cyanidin_3-O-beta-D-glucoside <=> p-coumaric_acid + cyanidin_3,7-di-O-beta-D-glucoside
|
2.4.1.300
cyanidin 3-O-glucoside 7-O-glucosyltransferase (acyl-glucose)
|
–
|
|
|
BRENDA:
BS422273
|
|
|
|
5-O-[(2E)-3-(4-hydroxyphenyl)prop-2-enoyl]-alpha-L-arabinofuranosyl-(1->3)-[beta-D-xylopyranosyl-(1->4)]-beta-D-xylopyranosyl-(1->4)-D-xylopyranose + H2O <=> O-beta-D-xylopyranosyl-(1,4)-O-alpha-L-arabinofuranosyl-(1,3)-O-beta-D-xylopyranosyl-(1,4)-D-xylopyranose + p-coumaric_acid
|
3.1.1.B10
|
–
|
|
|
BRENDA:
BS435671
|
|
|
|
coniferyl_p-coumarate + H2O <=> p-coumaric_acid + coniferyl_alcohol
|
3.1.1.73
feruloyl esterase
|
–
|
|
|
BRENDA:
BS391683
|
|
|
|
L-tyrosine <=> p-coumaric_acid
|
5.4.3.6
tyrosine 2,3-aminomutase
|
–
|
|
|
BRENDA:
BS409730
|
|
|
|
p-coumaric_acid <=> 4-vinylphenol
|
4.1.1.102
phenacrylate decarboxylase
|
–
|
|
|
BRENDA:
BS444760
|
|
|
|
trans-cinnamate + H+ + O2 + NADPH <=> H2O + NADP+ + p-coumaric_acid
|
1.14.14.91
trans-cinnamate 4-monooxygenase
|
–
|
|
|
SABIO-RK:
2223
|
|